Ion-Selective Intercalation Membranes and Method of Preparation

An electrochemical cell includes a positive electrode, a negative electrode, an electrolyte disposed between the positive electrode and the negative electrode, and an ion-conducting composite membrane disposed between the positive electrode and the negative electrode. The composite membrane includes a porous substrate having pores and a porosity from about 5 vol % to about 80 vol %, and a selective ion-conductive filler disposed at least partially within the pores. The filler includes an intercalation material. Methods of making the ion-conducting composite membrane and using an electrochemical cell having the ion-conducting composite membrane are also provided.